Sims are people to and they get lonely and need someone to be with. This article will help your Sim find a mate to spend loads of time with and be happy.

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[edit] Steps

If you have The Sims 2: Nightlife, call the matchmaker and ask for a blind date.
Whether you are on a date or not, talk to the person, watch how they react. Do they make faces and cross their arms, or do they clap their hands and smile? If they don't get along conversation wise, find someone else.
Invite the Sim over often, or chat on the phone. Have plenty of things available to your guest. Things like food, comfort, clean bathroom, things to do, etc
Make the other Sim feel special. Flirt, appreciate, hug, and kiss. Beware though, some Sims take longer than others to accept hugs and kisses.
When the Sims have a good relationship, propose to the other Sim to move in. This will bring them even closer to each other.
Propose, or just be friends, your choice.
Walk up to the Sim and click on the bright green circle around their feet.
Most of the time if you're in free play, the relationship will start at 20 and if so you will need to be nice and friendly and try not to come on too strong. If you decide to come on too strong, at the top of the screen there will be a note that says "how many times do I have to reject you before you take the hint."
If, while you're in a conversation, things come up as you scroll down you come across things that say Check Out Hit On or Charm click on them that lets the Sim know you want to be with them.
When things start going smoother, you will see things that read smooch, serenade, caress flying hug and a few more that lets you know you're a short path from marriage.
Finally, your bond should be very strong and you should be able to propose. If they reject you, keep on trying.

[edit] Or Try This

Create A New Sim, Appearance doesn't matter (just try to match the Turn-Ons of the Sim you need a mate for and not the Turn-Offs).
Make Him/Her have Turn-Ons and Offs that match your Sim you need a mate for. Choose a zodiac that is compatible with the mate's (check snootysims.com for compatible zodiacs)
Choose the SAME aspiration as the one you need a mate for.
Move him/her into the other person's house. Have them talk and tell jokes for a while. When they are friends, have them flirt appreciate and kiss.
Eventually you can get them married or just have a little premarital WOOHOO.

[edit] Tips

There is benefits in bringing someone into the family, income is a big one. Bringing in other family members in an option, bring kids in the family to
Don't try to rush things fast with the Sims, but do speed up the process.